5) Ghirahim from Skyward Sword. This guy is in my opinion, the best villain to enter the Zelda series. He's cocky, he's flamboyant, he's nonchalant but still straight up evil at the same time. His design is really cool imo, his voice is awesome, he is just... awesome XD
4) Apollo Justice from the Ace Attorney series. This guy represents success and determination for me. He's a defense lawyer who's relatively new to his profession. He's got the energy of a pro though, and can find out what somebody is hiding better than any other lawyer. He has deep care for his friends, as seen in duel destinies.
3) Dark Pit from Kid Icarus Uprising. This guy is everything I would want in an antihero doppelganger. His intentions are pure, but he's quiet and independent, and takes his tasks very seriously. He helps the protagonist only because he needs to keep him safe in order to exist. He's got a big heart behind that tough exterior, and did I mention how cool his lines are in his game?
2) Morgan from Fire Emblem Awakening. Particularly the female Morgan, as I haven't seen all of the support conversations for male Morgan. Morgan is the daughter of the avatar character, always being the opposite gender of what you chose to be in the game. She has a happy and optimistic outlook on life. She loves making her comrades happy, but also loves to play tricks and goof off. Her other half is a hard worker who aspires to be a great tactician like her father. The combination of compassion, diligence, and playfulness put her at the #2 spot
1) Riki the Heropon from Xenoblade Chronicles. Riki is often the character to provide a lot of the laughs in the game, second to Reyn. He's goofy and speaks in a bit of broken speech, but underneath lies a heart of gold. The conversations he has with other characters in the game could bring a tear to anyone's eye. Not only that, he's an incredibly good character in terms of playability as well. Who wouldn't love this little fur ball, as Reyn would call him XD