Here we go a review on your latest piece. Don't expect it to be a great review though.
First off, yes, from our viewing, the left leg looks thicker than her other leg, and looks awkward. Legs shouldn't be so square shaped either. The human body is pretty round, and it's usually made up of ovals, and triangles, not so much squares and rectangles.
Her hands look odd and mishapen. I can relate if you say they are a pain in the ass to draw, cause they are. Practice drawing hands on a blank canvas. Also, (again from my viewing), her right wrist shouldn't bend fully like that. It kinda looks like she broke it. Also, she is missing a sleeve on her right arm.
The torso is pretty okay, but it probably could be curvier due to the fact that she is female, but it's not my character so I have no say in this.
Her face looks too round in my opinion, but this is my opinion, and it could be just the way you draw heads, your own style.
If you want some help with poses, this is a great site for them :
http://www.posemaniacs.com/archives/1514
That's all I got for you. Hope this helps and remember to never stop drawing. c: